Many Mg–Mg bonds form the core of the Mg16Cp*8Br4K cluster anion: the key to a reassessment of the Grignard reagent (GR) formation process?
Abstract
It caused a sensation eight years ago, when the first room temperature stable molecular compound with a Mg–Mg bond (LMgMgL, L = chelating ligand) containing magnesium in the oxidation state +1 was prepared.
Document Details
- Document Type
- Pub Defense Publication
- Publication Date
- Jan 01, 2016
- Source ID
- 10.1039/c5sc03914b
Entities
People
- F. Henke
- H. Schnöckel
- K. H. Bowen
- M. Neumaier
- T. Kruczyński
Organizations
- Air Force Office of Scientific Research
- German Research Foundation
- Institute of Inorganic Chemistry
- Johns Hopkins University
- Karlsruhe Institute of Technology
- Office of Naval Research
- United States Army
- Yusuf Hamied Department of Chemistry