Heavily doped Au25–xAgx(SC6H11)18− nanoclusters: silver goes from the core to the surface

Abstract

The Au25(SR)18 nanocluster (where R = c-C6H11) can be heavily doped with silver through Ag(i)–thiolate complex induced size/structure transformation of Au23(SR)16− into Au25–xAgx(SR)18−.

Document Details

Document Type
Pub Defense Publication
Publication Date
Jan 01, 2016
Source ID
10.1039/c6cc01243d

Entities

People

  • Anindita Das
  • Kelly J. Lambright
  • Kristin Kirschbaum
  • Qi Li
  • Rongchao Jin
  • Shuxin Wang

Organizations

  • Air Force Office of Scientific Research
  • Carnegie Mellon University
  • United States Army
  • University of Toledo
  • Yusuf Hamied Department of Chemistry