Acceleration of metal–ligand complexation kinetics by electrospray ionization
Abstract
Electrospray ionization mass spectrometry (ESI-MS) is demonstrated to significantly accelerate the kinetics of metal–ligand complexation, with the formation rate constant increasing by more than an order of magnitude over previously determined solution-phase values.
Document Details
- Document Type
- Pub Defense Publication
- Publication Date
- Jan 01, 2017
- Source ID
- 10.1039/c7an01142c
Entities
People
- Aurora E Clark
- Austen Davis
- Brian H Clowers
- Morgan Kelley
- Sue B. Clark
Organizations
- Defense Threat Reduction Agency
- Pacific Northwest National Laboratory
- United States Army
- Washington State University
- Yusuf Hamied Department of Chemistry