Synthesis of Bi2−2xSb2xS3 (0 ≤ x ≤ 1) solid solutions from solventless thermolysis of metal xanthate precursors

Abstract

Tris(O-ethylxanthate)bismuth(iii) (1) and tris(O-ethylxanthate)antimony(iii) (2) were synthesized and used as precursors for the preparation of Bi2−2xSb2xS3 alloys (x = 0, 0.2, 0.4, 0.6, 0.8 and 1) using melt reactions.

Document Details

Document Type
Pub Defense Publication
Publication Date
Jan 01, 2018
Source ID
10.1039/c8tc02374c

Entities

People

  • Daniel J Kelly
  • David J. Lewis
  • Malik Dilshad Khan
  • Paul O'Brien
  • Sarah Jane Haigh
  • Tahani Alqahtani

Organizations

  • Defense Threat Reduction Agency
  • Engineering and Physical Sciences Research Council
  • European Research Council
  • School of Materials, University of Manchester
  • University of Kentucky
  • University of Manchester

Tags

Fields of Study

  • Materials science