Au2+ cannot catalyze conversion of methane to ethene at low temperature

Abstract

The previously reported conversion of methane to ethene catalyzed by Au2+ at thermal energies is investigated through a combination of experiment and theory. The conversion is found not to occur, in-line with well-established thermodynamics.

Document Details

Document Type
Pub Defense Publication
Publication Date
Jan 01, 2019
Source ID
10.1039/c9cy00523d

Entities

People

  • Albert A Viggiano
  • Brendan C Sweeny
  • Cameron J Owen
  • Hanqing Pan
  • Hua Guo
  • Nicholas R. Keyes
  • Nicholas S Shuman
  • Peter Armentrout
  • Shaun G Ard

Organizations

  • Air Force Office of Scientific Research
  • Air Force Research Laboratory
  • Boston College
  • Kirtland Air Force Base
  • National Academies of Sciences, Engineering, and Medicine
  • National Research Council
  • United States Army
  • University of New Mexico
  • University of Utah
  • Yusuf Hamied Department of Chemistry

Tags

Readers

  • Computational Modeling and Simulation
  • Nanoscale Plasmonic Nanotechnology
  • Organic Chemistry