Isolation of hydrazine oxidation products via halogen bonding: C–I bond scission and crystal polymorphism
Abstract
Reaction of methyl- or 1,1-dimethylhydrazine and iodofluorobenzenes yield cocrystals of sym-hexahydro-1,4-dimethyltetrazine or tetramethylammonium iodide (NMe4I) respectively, being polymorphic or of varying stoichiometry to those direct from NMe4I.
Document Details
- Document Type
- Pub Defense Publication
- Publication Date
- Jan 01, 2021
- Source ID
- 10.1039/d0ce01568g
Entities
People
- Andrew J Peloquin
- Colin D McMillen
- Khadijatul Kobra
- Scott T Iacono
- William T. Pennington
Organizations
- Air Force Institute of Technology
- Air Force Office of Scientific Research
- Clemson University
- United States Air Force Academy
- United States Army
- Yusuf Hamied Department of Chemistry