Incorporation of coinage metal–NHC complexes into heptaphosphide clusters

Abstract

A Me3Si-protected P7 cage reacts with N-heterocyclic-carbene complexes of coinage metals to yield a mononuclear Cu(i) complex featuring a Cu(η4-P7) core and a trinuclear Au(i) complex with linearly coordinated metal ions attached to the P7 cluster.

Document Details

Document Type
Pub Defense Publication
Publication Date
Jan 01, 2020
Source ID
10.1039/d0dt03119d

Entities

People

  • Alina Dragulescu-andrasi
  • Andrey Yu Rogachev
  • Jingbai Li
  • Mikhail Shatruk
  • Minyoung Jo

Organizations

  • Division of Chemistry
  • Florida State University
  • Illinois Institute of Technology
  • United States Army
  • United States Department of Defense
  • Yusuf Hamied Department of Chemistry

Tags

Fields of Study

  • Chemistry

Readers

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