Peculiar bond characters of fivefold coordinated octet compound crystals
Abstract
A refreshed view of chemical bonds in solids unveils unusual bonding in fivefold coordinated bulk crystals of octet compounds: out-of-plane cation–anion chain bonding via overlapping pz orbitals replaces in-plane π bonding of the isolated monolayer.
Document Details
- Document Type
- Pub Defense Publication
- Publication Date
- Jan 01, 2020
- Source ID
- 10.1039/d0sc00292e
Entities
People
- An-an Sun
- Gong Gu
- Min H. Kao
- Shang-Peng Gao
Organizations
- Army Research Office
- Division of Materials Research
- Fudan University
- Natural Science Foundation of Shanghai
- Shanghai Municipal Education Commission
- United States Army
- University of Tennessee