Sterically controlled reductive oligomerisations of CO by activated magnesium(i) compounds: deltate vs. ethenediolate formation

Abstract

Subtle changes to the bulk of 1 : 1 adducts of DMAP with magnesium(i) complexes leads to steric control over the products arising from their reductive oligomerisations of carbon monoxide.

Document Details

Document Type
Pub Defense Publication
Publication Date
Jan 01, 2020
Source ID
10.1039/d0sc00836b

Entities

People

  • Cameron Jones
  • Dafydd D L Jones
  • Iskander Douair
  • K Yuvaraj
  • Laurent Maron

Organizations

  • Australian Research Council
  • Monash University
  • Science and Engineering Research Board
  • United States Air Force
  • University of Toulouse (1896-1968)

Tags

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry