Transition-metal-mediated reduction and reversible double-cyclization of cyanuric triazide to an asymmetric bitetrazolate involving cleavage of the six-membered aromatic ring
Abstract
Cyanuric triazide reacts with transition metal precursors, extruding N2 and reducing the ligand by two electrons, which breaks an aromatic ring and rearranges to a bitetrazolylmethanediiminate (biTzI2−) ligand, forming two new aromatic rings.
Document Details
- Document Type
- Pub Defense Publication
- Publication Date
- Jan 01, 2021
- Source ID
- 10.1039/d0sc04949b
Entities
People
- Alex N. Byrne
- Claude Franklin Goldsmith
- Michael J. Zdilla
- Shivaiah Vaddypally
- Vitaly G. Kiselev
Organizations
- Brown University
- Division of Chemistry
- National Science Foundation
- Novosibirsk State University
- Office of Naval Research Global
- Russian Science Foundation
- Temple University