Statistical analysis of C–H activation by oxo complexes supports diverse thermodynamic control over reactivity
Abstract
Statistical analysis of transition metal oxo mediated C–H activation indicates that thermodynamic factors dictate reactivity and that the energetics of proton and electron transfer have effects independent of the free energy of the reaction.
Document Details
- Document Type
- Pub Defense Publication
- Publication Date
- Jan 01, 2021
- Source ID
- 10.1039/d0sc06058e
Entities
People
- John S. Anderson
- Joseph E. Schneider
- McKenna K. Goetz
Organizations
- Alfred P. Sloan Foundation
- Division of Chemistry
- National Institute of General Medical Sciences
- United States Army
- United States Department of Defense
- University of Chicago
- Yusuf Hamied Department of Chemistry