Solvate sponge crystals of (DMF)3NaClO4: reversible pressure/temperature controlled juicing in a melt/press-castable sodium-ion conductor
Abstract
Stimuli-responsive “solvate-sponge”-(DMF)3NaClO4 exhibits linear chains of DMF–Na+ ions with ClO4− anions in the interstitial space. At increased pressure or temperature, DMF is expelled (reversibly), resulting in a new stoichiometry-(DMF)2NaClO4.
Document Details
- Document Type
- Pub Defense Publication
- Publication Date
- Jan 01, 2021
- Source ID
- 10.1039/d0sc06455f
Entities
People
- Arun Venkatnathan
- Birane Fall
- Michael J. Zdilla
- Prabhat Prakash
- Shylendran Ardhra
- Stephanie L Wunder
Organizations
- Department of Science and Technology
- Indian Institute of Science Education and Research, Pune
- National Science Foundation
- Science and Engineering Research Board
- Temple University
- United States Army
- United States Army Research Laboratory
- United States Department of Energy
- Yusuf Hamied Department of Chemistry