Effect of water frustration on water oxidation catalysis in the nanoconfined interlayers of layered manganese oxides birnessite and buserite
Abstract
Reacting out of frustration: unlike buserite, the nanoconfined interlayer of birnessite results in geometric frustration of water molecules, which decreases the Marcus reorganization energy of electron transfer and enhances water oxidation catalysis.
Document Details
- Document Type
- Pub Defense Publication
- Publication Date
- Jan 01, 2021
- Source ID
- 10.1039/d0ta09635k
Entities
People
- Michael J. Zdilla
- Michael L. Klein
- Ravneet K. Bhullar
- Richard C Remsing
Organizations
- Division of Chemistry
- National Science Foundation
- Office of Basic Energy Sciences
- Rutgers University
- Temple University
- United States Army
- United States Army Research Laboratory
- Yusuf Hamied Department of Chemistry