One dimensional halogen bond design: Br⋯N versus I⋯N with fluoroarenes
Abstract
29 structures of 1,4-dibromo- and 1,4-diiodotetrafluorobenzene, as well as 4,4′-dibromo- and 4,4′-diiodooctafluorobiphenyl with bifunctional amines were synthesized, exposing correlations of halogen bond length with both electrostatic potential and percent buried volume.
Document Details
- Document Type
- Pub Defense Publication
- Publication Date
- Jan 01, 2021
- Source ID
- 10.1039/d1ce00864a
Entities
People
- Andrew J Peloquin
- Colin D McMillen
- William T. Pennington
Organizations
- Air Force Institute of Technology
- Air Force Office of Scientific Research
- Clemson University