Stabilization of pentazolate anions in the high-pressure compounds Na2N5and NaN5and in the sodium pentazolate framework NaN5·N2

Abstract

Three oxygen-free pentazolate salts Na2N5, NaN5and NaN5·N2were synthesized from sodium azide NaN3and molecular nitrogen N2at 50 GPa.

Document Details

Document Type
Pub Defense Publication
Publication Date
Jan 01, 2021
Source ID
10.1039/d1dt00722j

Entities

People

  • Alexander Goncharov
  • Elena Bykova
  • Iskander G. Batyrev
  • Maxim Bykov
  • Mohammad F. Mahmood
  • Stella Chariton
  • Vitali Prakapenka

Organizations

  • Argonne National Laboratory
  • Carnegie Institution for Science
  • Howard University
  • National Science Foundation
  • United States Army
  • United States Army Research Laboratory
  • University of Chicago
  • Washington University in St. Louis

Tags

Readers

  • Military Engineering.
  • Organic Chemistry