Stereoelectronic and dynamical effects dictate nitrogen inversion during valence isomerism in benzene imine

Abstract

Non-classical processes such as heavy-atom tunneling and post transition-state dynamics govern stereoselectivity for benzene imine ⇌ 1H-azepine.

Document Details

Document Type
Pub Defense Publication
Publication Date
Jan 01, 2022
Source ID
10.1039/d1sc04855d

Entities

People

  • Ankita Das
  • Ayan Datta
  • Chandralekha Hajra
  • Nilangshu Mandal

Organizations

  • Council of Scientific and Industrial Research
  • Indian Association for the Cultivation of Science
  • Science and Engineering Research Board

Tags

Fields of Study

  • Chemistry

Readers

  • Polymer Science and Technology
  • Quantum Chemistry
  • Theoretical Analysis.