Layered structures of assembled imine-linked macrocycles and two-dimensional covalent organic frameworks give rise to prolonged exciton lifetimes

Abstract

Excitonic dynamics studies of a 2D COF, its corresponding hexagonal macrocycle, and extended nanotubes comprised of stacked macrocycles reveal that layering of the macrocycle in the assembled COF and nanotube lead to a prolonged exciton lifetime.

Document Details

Document Type
Pub Defense Publication
Publication Date
Jan 01, 2022
Source ID
10.1039/d1tc05840a

Entities

People

  • Austin P Spencer
  • Brian T Phelan
  • Dillon O. Edwards
  • George C. Schatz
  • Lin Chen
  • Matthew S Kirschner
  • Matthew S. Kelley
  • Michael J Strauss
  • Nathan C Flanders
  • Pyosang Kim
  • Rebecca L Li
  • Richard D. Schaller
  • Waleed Helweh
  • Wang Shiwei
  • William Dichtel

Organizations

  • Argonne National Laboratory
  • Army Research Office
  • National Science Foundation
  • Northwestern University
  • Office of Basic Energy Sciences
  • Office of Naval Research

Tags

Fields of Study

  • Chemistry

Readers

  • Nanoscale Plasmonic Nanotechnology
  • Organic Chemistry
  • Quantum spin resonance or Electron Paramagnetic Resonance spectroscopy.

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene