Exploring mechanistic routes for light alkane oxidation with an iron–triazolate metal–organic framework

Abstract

An iron–triazolate metal–organic framework (MOF) is computationally investigated for the catalytic oxidation of strong C–H bonds. The MOF is predicted to form reactive iron-oxo active sites, and design rules to guide future experiments are discussed.

Document Details

Document Type
Pub Defense Publication
Publication Date
Jan 01, 2022
Source ID
10.1039/d2cp00963c

Entities

People

  • Andrew S Rosen
  • Justin M Notestein
  • Randall Q. Snurr

Organizations

  • Northwestern University
  • Office of Basic Energy Sciences
  • United States Department of Energy

Tags

Readers

  • Computational Modeling and Simulation
  • Organic Chemistry
  • Solar Photovoltaics and Thermoelectric Devices.