Controlled monodefluorination and alkylation of C(sp3)–F bonds by lanthanide photocatalysts: importance of metal–ligand cooperativity
Abstract
The controlled functionalization of a single fluorine in a CF3group is difficult and rare. Photochemical C–F bond functionalization is achieved using catalysts made from a range of earth-abundant lanthanides by using a ligand that enables M–L cooperativity.
Document Details
- Document Type
- Pub Defense Publication
- Publication Date
- Jan 01, 2022
- Source ID
- 10.1039/d2sc04192h
Entities
People
- Addison N Desnoyer
- Amy E Kynman
- Andrea Di Giuseppe
- Laurent Maron
- Laurent Sévery
- Luca K. Elghanayan
- Polly Arnold
- T. Don Tilley
- Yan Yang
Organizations
- Chinese Academy of Sciences
- Engineering and Physical Sciences Research Council
- Lawrence Berkeley National Laboratory
- National Institutes of Health
- Office of Basic Energy Sciences
- University of Edinburgh
- University of Toulouse (1896-1968)
- Yusuf Hamied Department of Chemistry