Insights into dual-functional modification for water stability enhancement of mesoporous zirconium metal–organic frameworks

Abstract

This study revealed dual functions of the installed Facac ligands: enhancement of framework mechanical stability due to electrostatic interactions; and weaker capillary forces evaluated from free energies of dehydration during water evacuation.

Document Details

Document Type
Pub Defense Publication
Publication Date
Jan 01, 2022
Source ID
10.1039/d2ta03851j

Entities

People

  • Andreas Stein
  • Diego A Gómez-Gualdrón
  • Jian Liu
  • Joseph T. Hupp
  • Kevin M. Schmalbach
  • Nathan A. Mara
  • Neil M. Schweitzer
  • Ryther Anderson
  • Thomas R. Sheridan
  • Zhao Wang

Organizations

  • Colorado School of Mines
  • Division of Materials Research
  • National Science Foundation
  • Northwestern University
  • United States Department of Energy
  • University of Minnesota

Tags

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Quantum Chemistry
  • Thin Film Deposition Science.