Variable temperature kinetic isotope effects demonstrate extensive tunnelling in the C–H activation reactivity of a transition metal-oxo complex
Abstract
The role of proton tunnelling in imbalanced CPET reactions has been a point of debate recently; VT-KIE measurements suggest there is extensive tunnelling in this reactivity for a Co-oxo complex.
Document Details
- Document Type
- Pub Defense Publication
- Publication Date
- Jan 01, 2023
- Source ID
- 10.1039/d3cc02130k
Entities
People
- John S. Anderson
- Joseph E. Schneider
- McKenna K. Goetz
Organizations
- Alfred P. Sloan Foundation
- National Institute of General Medical Sciences
- The Camille and Henry Dreyfus Foundation
- University of Chicago
- University of Wisconsin–Madison