Role of carboxylates in the phase determination of metal sulfide nanoparticles

Abstract

At low carboxylate concentrations the sulfur source is highly reactive thiourea, which gives rise to sulfur rich nanoparticles. At high carboxylate concentrations, the sulfur source is the less reactive thiocyanate, resulting in sulfur poor phases.

Document Details

Document Type
Pub Defense Publication
Publication Date
Jan 01, 2023
Source ID
10.1039/d3nh00227f

Entities

People

  • Andrey A. Shults
  • Guanyu Lu
  • Janet E. Macdonald
  • Joshua D Caldwell

Organizations

  • National Science Foundation
  • Office of Naval Research
  • Vanderbilt University

Tags

Readers

  • Nanocomposite Materials Science
  • Organic Chemistry

Technology Areas

  • Biotechnology