Molybdenum carbonyl assisted reductive tetramerization of CO by activated magnesium(i) compounds: squarate dianion vs. metallo-ketene formation
Abstract
The reductive tetramerisation of CO by Lewis base activated dimagnesium(i) compounds, in the presence of Mo(CO)6, led to the competitive formation of magnesium squarate and metallo-ketene complexes (see picture).
Document Details
- Document Type
- Pub Defense Publication
- Publication Date
- Jan 01, 2023
- Source ID
- 10.1039/d3sc01487h
Entities
People
- Cameron Jones
- Iskander Douair
- Jeremy C. Mullins
- K Yuvaraj
- Laurent Maron
- Thayalan Rajeshkumar
Organizations
- Air Force Office of Scientific Research
- Alexander von Humboldt Foundation
- Australian Research Council
- Monash University
- University of Toulouse (1896-1968)