Synthesis and Optoelectronic Properties of Iptycene–Naphthazarin Dyes
Abstract
We report the synthesis and characterization of iptycene–naphthazarin dyes by using a sequential Diels–Alder approach. The tautomerization of naphthazarin was used as the key step in the synthesis, with structures confirmed by single-crystal X-ray and NMR analysis. The systematic trends in electronic properties were investigated by UV/Vis spectroscopy. BF2 complexes of the dyes were prepared by reaction with BF3·OEt2 in CH2Cl2.
Document Details
- Document Type
- Pub Defense Publication
- Publication Date
- Dec 04, 2018
- Source ID
- 10.1055/s-0037-1611169
Entities
People
- Cagatay Dengiz
- Timothy M. Swager
- You-chi Wu
Organizations
- Air Force Office of Scientific Research
- Massachusetts Institute of Technology
- Middle East Technical University