Characterization of self-propagating formation reactions in Ni/Zr multilayered foils using reaction heats, velocities, and temperature-time profiles
Abstract
We report on intermetallic formation reactions in vapor-deposited multilayered foils of Ni/Zr with 70 nm bilayers and overall atomic ratios of Ni:Zr, 2 Ni:Zr, and 7 Ni:2 Zr. The sequence of alloy phase formation and the stored energy is evaluated at slow heating rates (∼1 K/s) using differential scanning calorimetry traces to 725 °C. All three chemistries initially form a Ni–Zr amorphous phase which crystallizes first to the intermetallic NiZr. The heat of reaction to the final phase is 34–36 kJ/mol atom for all chemistries. Intermetallic formation reactions are also studied at rapid heating rates (greater than 105 K/s) in high temperature, self-propagating reactions which can be ignited in these foils by an electric spark. We find that reaction velocities and maximum reaction temperatures (Tmax) are largely independent of foil chemistry at 0.6±0.1 m/s and 1220±50 K, respectively, and that the measured Tmax is more than 200 K lower than predicted adiabatic temperatures (Tad). The difference between Tmax and Tad is explained by the prediction that transformation to the final intermetallic phases occurs after Tmax and results in the release of 20%–30% of the total heat of reaction and a delay in rapid cooling.
Document Details
- Document Type
- Pub Defense Publication
- Publication Date
- Jan 01, 2011
- Source ID
- 10.1063/1.3527925
Entities
People
- Natalie Walker
- R. Knepper
- S. C. Barron
- Timothy P. Weihs
Organizations
- Johns Hopkins University
- Office of Naval Research
- United States Department of Energy