Influence of V/III growth flux ratio on trap states in m-plane GaN grown by ammonia-based molecular beam epitaxy

Abstract

Deep level transient spectroscopy (DLTS) and deep level optical spectroscopy (DLOS) were utilized to investigate the behavior of deep states in m-plane, n-type GaN grown by ammonia-based molecular beam epitaxy (NH3-MBE) as a function of systematically varied V/III growth flux ratios. Levels were detected at EC − 0.14 eV, EC − 0.21 eV, EC − 0.26 eV, EC − 0.62 eV, EC − 0.67 eV, EC − 2.65 eV, and EC − 3.31 eV, with the concentrations of several traps exhibiting systematic dependencies on V/III ratio. The DLTS spectra are dominated by traps at EC − 0.14 eV and EC − 0.67 eV, whose concentrations decreased monotonically with increasing V/III ratio and decreasing oxygen impurity concentration, and by a trap at EC − 0.21 eV that revealed no dependence of its concentration on growth conditions, suggestive of different physical origins. Higher concentrations of deeper trap states detected by DLOS with activation energies of EC − 2.65 eV and EC − 3.31 eV in each sample did not display measureable sensitivity to the intentionally varied V/III ratio, necessitating further study on reducing these deep traps through growth optimization for maximizing material quality of NH3-MBE grown m-plane GaN.

Document Details

Document Type
Pub Defense Publication
Publication Date
Oct 08, 2012
Source ID
10.1063/1.4759037

Entities

People

  • Aaron R. Arehart
  • Christophe A. Hurni
  • James S. Speck
  • Steven A. Ringel
  • Zhicai Zhang

Organizations

  • Office of Naval Research
  • Ohio State University
  • University of California

Tags

Fields of Study

  • Materials science

Readers

  • Marine Ecological Systems Migration
  • Semiconductor Device Technology