Reversible superconductivity in electrochromic indium-tin oxide films

Abstract

Transparent conductive indium tin oxide (ITO) thin films, electrochemically intercalated with sodium or other cations, show tunable superconducting transitions with a maximum Tc at 5 K. The transition temperature and the density of states, D(EF) (extracted from the measured Pauli susceptibility χp) exhibit the same dome shaped behavior as a function of electron density. Optimally intercalated samples have an upper critical field ≈ 4 T and Δ/kBTc ≈ 2.0. Accompanying the development of superconductivity, the films show a reversible electrochromic change from transparent to colored and are partially transparent (orange) at the peak of the superconducting dome. This reversible intercalation of alkali and alkali earth ions into thin ITO films opens diverse opportunities for tunable, optically transparent superconductors.

Document Details

Document Type
Pub Defense Publication
Publication Date
Dec 17, 2012
Source ID
10.1063/1.4772536

Entities

People

  • Ali E Aliev
  • Ka Xiong
  • Kyeongjae Cho
  • M. B. Salamon

Organizations

  • Air Force Office of Scientific Research
  • Seoul National University
  • University of Texas at Dallas

Tags

Fields of Study

  • Physics

Readers

  • Materials Science and Engineering.
  • Quantum spin resonance or Electron Paramagnetic Resonance spectroscopy.
  • Thin Film Deposition Science.

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene