Infinite swapping replica exchange molecular dynamics leads to a simple simulation patch using mixture potentials

Abstract

Replica exchange molecular dynamics (REMD) becomes more efficient as the frequency of swap between the temperatures is increased. Recently Plattner et al. [J. Chem. Phys. 135, 134111 (2011)10.1063/1.3643325] proposed a method to implement infinite swapping REMD in practice. Here we introduce a natural modification of this method that involves molecular dynamics simulations over a mixture potential. This modification is both simple to implement in practice and provides a better, energy based understanding of how to choose the temperatures in REMD to optimize efficiency. It also has implications for generalizations of REMD in which the swaps involve other parameters than the temperature.

Document Details

Document Type
Pub Defense Publication
Publication Date
Feb 26, 2013
Source ID
10.1063/1.4790706

Entities

People

  • Eric Vanden-Eijnden
  • Jianfeng Lu

Organizations

  • Duke University
  • National Science Foundation
  • New York University
  • Office of Naval Research

Tags

Readers

  • Calculus or Mathematical Analysis
  • Materials Science and Engineering.
  • Solar Photovoltaics and Thermoelectric Devices.