Electronic structure of boron doped diamond: An x-ray spectroscopic study

Abstract

The valence and conduction band electronic structure of boron-doped diamond has been measured using soft x-ray emission and absorption spectroscopy. The experimental results reveal p-type doping in the diamond film through the appearance of states in the band-gap. Structure distortion was observed around the doping center, while the long range order of the diamond structure remains. A chemically shifted C 1s level explains why one of the absorption features seems to appear below the valence band maximum. An excitonic feature was observed in the boron-doped diamond, similar to that observed in pure diamond, indicating that the exciton binding energy remains the same upon B-doping.

Document Details

Document Type
Pub Defense Publication
Publication Date
Apr 22, 2013
Source ID
10.1063/1.4802814

Entities

People

  • A. De Battisti
  • J.-h. Guo
  • K. E. Smith
  • M. Mattesini
  • P.-a. Glans
  • R. Ahuja
  • S. Ferro
  • T. Learmonth

Organizations

  • Advanced Light Source
  • Army Research Office
  • Boston University
  • Complutense University of Madrid
  • United States Department of Energy
  • University of Ferrara
  • Uppsala University

Tags

Fields of Study

  • Materials science
  • Physics

Readers

  • Semiconductor Device Technology
  • Theoretical Analysis.

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene