Low resistivity, super-saturation phosphorus-in-silicon monolayer doping

Abstract

We develop a super-saturation technique to extend the previously established doping density limit for ultra-high vacuum monolayer doping of silicon with phosphorus. Through an optimized sequence of PH3 dosing and annealing of the silicon surface, we demonstrate a 2D free carrier density of ns = (3.6 ± 0.1) × 1014 cm−2, ∼50% higher than previously reported values. We perform extensive characterization of the dopant layer resistivity, including room temperature depth-dependent in situ four point probe measurements. The dopant layers remain conductive at less than 1 nm from the sample surface and importantly, surpass the semiconductor industry target for ultra-shallow junction scaling of <900 Ω◻−1 at a depth of 7 nm.

Document Details

Document Type
Pub Defense Publication
Publication Date
Mar 24, 2014
Source ID
10.1063/1.4869111

Entities

People

  • C. M. Polley
  • Giordano Scappucci
  • J. G. Keizer
  • M. Y. Simmons
  • S. R. Mckibbin

Organizations

  • Army Research Office
  • University of New South Wales

Tags

Fields of Study

  • Physics

Readers

  • Electrochemical Surface Science
  • Materials Science and Engineering.
  • Semiconductor Device Technology

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene