Electron-phonon coupling and thermal conductance at a metal-semiconductor interface: First-principles analysis

Abstract

The mechanism of heat transfer and the contribution of electron-phonon coupling to thermal conductance of a metal-semiconductor interface remains unclear in the present literature. We report ab initio simulations of a technologically important titanium silicide (metal)–silicon (semiconductor) interface to estimate the Schottky barrier height, and the strength of electron-phonon and phonon-phonon heat transfer across the interface. The electron and phonon dispersion relations of TiSi2 with C49 structure and the TiSi2-Si interface are obtained using first-principles calculations within the density functional theory framework. These are used to estimate electron-phonon linewidths and the associated Eliashberg function that quantifies coupling. We show that the coupling strength of electrons with interfacial phonon modes is of the same order of magnitude as coupling of electrons to phonon modes in the bulk metal, and its contribution to electron-phonon interfacial conductance is comparable to the harmonic phonon-phonon conductance across the interface.

Document Details

Document Type
Pub Defense Publication
Publication Date
Apr 03, 2015
Source ID
10.1063/1.4916729

Entities

People

  • Sridhar Sadasivam
  • Timothy S. Fisher
  • Umesh V. Waghmare

Organizations

  • Indo-US Science and Technology Forum
  • Jawaharlal Nehru Centre for Advanced Scientific Research
  • Office of Naval Research
  • Purdue University

Tags

Readers

  • Quantum Chemistry
  • Quantum spin resonance or Electron Paramagnetic Resonance spectroscopy.
  • Thin Film Deposition Science.

Technology Areas

  • Microelectronics