Atomic origin of high-temperature electron trapping in metal-oxide-semiconductor devices

Abstract

MOSFETs based on wide-band-gap semiconductors are suitable for operation at high temperature, at which additional atomic-scale processes that are benign at lower temperatures can get activated, resulting in device degradation. Recently, significant enhancement of electron trapping was observed under positive bias in SiC MOSFETs at temperatures higher than 150 °C. Here, we report first-principles calculations showing that the enhanced electron trapping is associated with thermally activated capturing of a second electron by an oxygen vacancy in SiO2 by which the vacancy transforms into a structure that comprises one Si dangling bond and a bond between a five-fold and a four-fold Si atoms. The results suggest a key role of oxygen vacancies and their structural reconfigurations in the reliability of high-temperature MOS devices.

Document Details

Document Type
Pub Defense Publication
Publication Date
Apr 06, 2015
Source ID
10.1063/1.4917528

Entities

People

  • Sarit Dhar
  • Sokrates T. Pantelides
  • Xiao Shen

Organizations

  • Auburn University
  • National Science Foundation
  • Oak Ridge National Laboratory
  • United States Army Research Laboratory
  • Vanderbilt University

Tags

Readers

  • Nanoscale Plasmonic Nanotechnology
  • Semiconductor Device Technology

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene