Two-band model interpretation of the p- to n-transition in ternary tetradymite topological insulators

Abstract

The requirement for large bulk resistivity in topological insulators has led to the design of complex ternary and quaternary phases with balanced donor and acceptor levels. A common feature of the optimized phases is that they lie close to the p- to n-transition. The tetradymite Bi2Te3−xSex system exhibits minimum bulk conductance at the ordered composition Bi2Te2Se. By combining local and integral measurements of the density of states, we find that the point of minimum electrical conductivity at x = 1.0 where carriers change from hole-like to electron-like is characterized by conductivity of the mixed type. Our experimental findings, which are interpreted within the framework of a two-band model for the different carrier types, indicate that the mixed state originates from different types of native defects that strongly compensate at the crossover point.

Document Details

Document Type
Pub Defense Publication
Publication Date
Jun 23, 2015
Source ID
10.1063/1.4922857

Entities

People

  • Bonnie W. Leung
  • D. Koumoulis
  • L.-s. Bouchard
  • Mercouri Kanatzidis
  • N. P. Calta
  • S.-h. Lo
  • Thomas C. Chasapis
  • V. P. Dravid

Organizations

  • Defense Advanced Research Projects Agency
  • Northwestern University
  • University of California, Los Angeles

Tags

Fields of Study

  • Materials science

Readers

  • Materials Science and Engineering.
  • Mathematical Modeling and Probability Theory.
  • Solar Photovoltaics and Thermoelectric Devices.

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene