Graphene/semiconductor silicon modified BiFeO3/indium tin oxide ferroelectric photovoltaic device for transparent self-powered windows

Abstract

We report photovoltaic response of highly transparent graphene/BiFe0.95Si0.05O3 (BFSiO)/ITO/glass derived from bottom-up spin coating technique. The device exhibits short-circuit-current (ISC 0.75 mA) with 1000 fold upsurge and open-circuit-voltage (VOC ∼ 0.45 V) under standard AM 1.5 illumination through graphene. In combination, ISC of 0.63 mA and VOC of 0.35 V for same illumination through ITO, reveals the prospects of harvesting indoor light. Also, crystallographic structure, red shift in band gap, leakage behavior, and ferroelectric characteristics of BFSiO thin films are reported. Reproducible transient response of ISC and VOC with quick switching (<100 ms) for 20 consecutive cycles and stability (95%) over test period of 16 weeks signifies high endurance and retentivity, promising for building integrated self-powered windows.

Document Details

Document Type
Pub Defense Publication
Publication Date
Aug 10, 2015
Source ID
10.1063/1.4928541

Entities

People

  • Gerardo Morell
  • Monika Tomar
  • Rajesh K. Katiyar
  • Ram S. Katiyar
  • Rohit Medwal
  • Shojan P. Pavunny
  • Surbhi Gupta
  • Tej B. Limbu
  • Vinay Gupta

Organizations

  • National Science Foundation
  • United States Department of Defense
  • University of Delhi
  • University of Puerto Rico

Tags

Fields of Study

  • Materials science

Readers

  • Materials Science and Engineering.
  • Nanocomposite Materials Science
  • Solar Photovoltaics and Thermoelectric Devices.

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene