Three-dimensional multimodal imaging and analysis of biphasic microstructure in a Ti–Ni–Sn thermoelectric material

Abstract

The three-dimensional microstructure of levitation melted TiNi1.20Sn has been characterized using the TriBeam system, a scanning electron microscope equipped with a femtosecond laser for rapid serial sectioning, to map the character of interfaces. By incorporating both chemical data (energy dispersive x-ray spectroscopy) and crystallographic data (electron backscatter diffraction), the grain structure and phase morphology were analyzed in a 155 μm × 178 μm × 210 μm volume and were seen to be decoupled. The predominant phases present in the material, half-Heusler TiNiSn, and full-Heusler TiNi2Sn have a percolated structure. The distribution of coherent interfaces and high-angle interfaces has been measured quantitatively.

Document Details

Document Type
Pub Defense Publication
Publication Date
Sep 01, 2015
Source ID
10.1063/1.4931764

Entities

People

  • Jason E. Douglas
  • McLean P. Echlin
  • Ram Seshadri
  • Tresa M. Pollock
  • William C. Lenthe

Organizations

  • Air Force Research Laboratory
  • National Science Foundation
  • University of California

Tags

Fields of Study

  • Materials science
  • Physics

Readers

  • Aerosol Science/Aerosol Physics
  • Manufacturing Engineering.
  • Thin Film Deposition Science.

Technology Areas

  • Directed Energy
  • Directed Energy - Pulsed-Laser Deposition
  • Microelectronics
  • Microelectronics - Graphene