Reversible electrochemical modulation of the superconducting transition temperature of LiTi2O4 ultrathin films by ionic liquid gating

Abstract

We demonstrate in situ modulation of the superconducting transition temperature (Tc) of LiTi2O4 thin films by ionic liquid gating. 15 nm thick LiTi2O4 thin films grown on MgAl2O4 substrates with the pristine Tc of 11.5 K was patterned into electric double-layer transistor devices for gating using ionic liquid with or without Li+ ions. The Tc of the LiTi2O4 thin film was found to decrease with a negative gate voltage for gating with either pure ionic liquid or Li+ containing ionic liquid. On the other hand, the recovery of Tc is observed at a positive gate voltage only for gating with the Li+ containing ionic liquid. The present observation suggests the possibility of reversible electrochemical modulation of superconducting properties by lithiation and delithiation.

Document Details

Document Type
Pub Defense Publication
Publication Date
Oct 05, 2015
Source ID
10.1063/1.4932551

Entities

People

  • I. Takeuchi
  • J. Felix Shin
  • K. Jin
  • R. L. Greene
  • R. Suchoski
  • Shigeo Maruyama
  • Shintaro Yasui
  • Xiaoxuan Zhang

Organizations

  • Air Force Office of Scientific Research
  • Division of Materials Research
  • Institute of Physics
  • Tohoku University
  • Tokyo Institute of Technology
  • University of Maryland

Tags

Fields of Study

  • Materials science
  • Physics

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Semiconductor Device Technology
  • Superconducting Magnet Technology