Flame speed enhancement of solid nitrocellulose monopropellant coupled with graphite at microscales

Abstract

The flame-speed-enhancement phenomenon of a solid monopropellant (nitrocellulose) using a highly conductive thermal base (graphite sheet) was demonstrated and studied both experimentally and theoretically. A propellant layer ranging from 20 μm to 170 μm was deposited on the top of a 20-μm thick graphite sheet. Self-propagating oscillatory combustion waves were observed, with average flame speed enhancements up to 14 times the bulk value. The ratio of the fuel-to-graphite layer thickness affects not only the average reaction front velocities but also the period and the amplitude of the combustion wave oscillations. To better understand the flame-speed enhancement and the oscillatory nature of the combustion waves, the coupled nitrocellulose-graphite system was modeled using one-dimensional energy conservation equations along with simple one-step chemistry. The period and the amplitude of the oscillatory combustion waves were predicted as a function of the ratio of the fuel-to-graphite thickness (R), the ratio of the graphite-to-fuel thermal diffusivity (α0), and the non-dimensional inverse adiabatic temperature rise (β). The predicted flame speeds and the characteristics of the oscillations agree well with the experimental data. The new concept of using a highly conductive thermal base such as carbon-based nano- and microstructures to enhance flame propagation speed or burning rate of propellants and fuels could lead to improved performance of solid and liquid rocket motors, as well as of the alternative energy conversion microelectromechanical devices.

Document Details

Document Type
Pub Defense Publication
Publication Date
Mar 04, 2016
Source ID
10.1063/1.4943226

Entities

People

  • Li Qiao
  • Omar R. Yehia
  • Shourya Jain

Organizations

  • Air Force Office of Scientific Research
  • Purdue University

Tags

Fields of Study

  • Physics

Readers

  • Atmospheric Science / Meteorology, specifically Wind Wave Turbulence.
  • Combustion science or combustion engineering.
  • Nanofabrication and Microfabrication.

Technology Areas

  • Microelectronics