Electrochemical kinetics and dimensional considerations, at the nanoscale
Abstract
It is shown that the consideration of the density of states variation in nanoscale electrochemical systems yields modulations in the rate constant and concomitant electrical currents. The proposed models extend the utility of Marcus-Hush-Chidsey (MHC) kinetics to a larger class of materials and could be used as a test of dimensional character. The implications of the study are of much significance to an understanding and modulation of charge transfer nanostructured electrodes.
Document Details
- Document Type
- Pub Defense Publication
- Publication Date
- Jun 01, 2016
- Source ID
- 10.1063/1.4955049
Entities
People
- H. Yamada
- P. R. Bandaru
Organizations
- Defense Advanced Research Projects Agency
- National Science Foundation
- University of California