Infrared dielectric function of polydimethylsiloxane and selective emission behavior

Abstract

The complex refractive index of polydimethylsiloxane (PDMS) is determined in the wavelength range between 2.5 μm and 16.7 μm. The parameters of a Drude-Lorentz oscillator model (with 15 oscillators) are extracted from Fourier transform infrared spectroscopy reflectance measurements made on both bulk PDMS and thin films of PDMS deposited on the gold coated silicon substrates. It is shown that thin films of PDMS atop gold exhibit selective emission in the 8 μm to 13 μm atmospheric transmittance window, which demonstrates that PDMS, especially due to its ease of deposition, may be a viable material for passive radiative cooling applications.

Document Details

Document Type
Pub Defense Publication
Publication Date
Aug 08, 2016
Source ID
10.1063/1.4961051

Entities

People

  • Arvind Narayanaswamy
  • Arvind Srinivasan
  • Braden Czapla
  • Jeff Mayo

Organizations

  • Columbia University
  • National Science Foundation
  • Office of Naval Research

Tags

Fields of Study

  • Physics

Readers

  • Polymer Science and Technology
  • Spectroscopy.
  • Surface Engineering/Surface Coating Technology.