Direct measurement of defect and dopant abruptness at high electron mobility ZnO homojunctions

Abstract

Due to a strong Fermi-level mismatch, about 10% of the electrons in a 5-nm-thick highly Ga-doped ZnO (GZO) layer grown by molecular beam epitaxy at 250 °C on an undoped ZnO buffer layer transfer to the ZnO (Debye leakage), causing the measured Hall-effect mobility (μH) of the GZO/ZnO combination to remarkably increase from 34 cm2/V s, in thick GZO, to 64 cm2/V s. From previous characterization of the GZO, it is known that ND = [Ga] = 1.04 × 1021 and NA = [VZn] = 1.03 × 1020 cm−3, where ND, NA, and [VZn] are the donor, acceptor, and Zn-vacancy concentrations, respectively. In the ZnO, ND = 3.04 × 1019 and NA = 8.10 × 1018 cm−3. Assuming the interface is abrupt, theory predicts μH = 61 cm2/V s, with no adjustable parameters. The assumption of abruptness in [Ga] and [VZn] profiles is confirmed directly with a differential form of depth-resolved cathodoluminescence spectroscopy coupled with X-ray photoelectron spectroscopy. An anneal in Ar at 500 °C for 10 min somewhat broadens the profiles but causes no appreciable degradation in μH and other electrical properties.

Document Details

Document Type
Pub Defense Publication
Publication Date
Oct 03, 2016
Source ID
10.1063/1.4963888

Entities

People

  • Chen Yang
  • D. C. Look
  • E. R. Heller
  • G. Faber
  • Geoffrey M. Foster
  • Leonard J Brillson
  • Y.-f. Yao

Organizations

  • Air Force Office of Scientific Research
  • Air Force Research Laboratory
  • National Science Foundation
  • National Science and Technology Council
  • National Taiwan University
  • Ohio State University
  • Wright State University

Tags

Fields of Study

  • Materials science

Readers

  • Semiconductor Device Technology

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene