Reducing graphene device variability with yttrium sacrificial layers

Abstract

Graphene technology has made great strides since the material was isolated more than a decade ago. However, despite improvements in growth quality and numerous “hero” devices, challenges of uniformity remain, restricting the large-scale development of graphene-based technologies. Here, we investigate and reduce the variability of graphene transistors by studying the effects of contact metals (with and without a Ti layer), resist, and yttrium (Y) sacrificial layers during the fabrication of hundreds of devices. We find that with optical photolithography, residual resist and process contamination are unavoidable, ultimately limiting the device performance and yield. However, using Y sacrificial layers to isolate the graphene from processing conditions improves the yield (from 73% to 97%), the average device performance (three-fold increase of mobility and 58% lower contact resistance), and the device-to-device variability (standard deviation of Dirac voltage reduced by 20%). In contrast to other sacrificial layer techniques, the removal of the Y sacrificial layer with dilute HCl does not harm surrounding materials, simplifying large-scale graphene fabrication.

Document Details

Document Type
Pub Defense Publication
Publication Date
May 29, 2017
Source ID
10.1063/1.4984090

Entities

People

  • Enrique A Carrion
  • Eric Pop
  • Maryann C. Tung
  • Ning C. Wang

Organizations

  • Air Force Office of Scientific Research
  • National Science Foundation
  • Stanford University
  • University of Illinois Urbana–Champaign

Tags

Readers

  • Materials Science and Engineering.
  • Quantum Dot Semiconductor Device Photonics and Graphene Optoelectronic Materials and THz Physics.
  • Semiconductor Device Technology

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene