Formation energies of native point defects in strained-layer superlattices

Abstract

The two most desired properties for photo-detection using a strained-layer superlattice (SLS) are high native point defect (NPD) formation energies and absence of mid-gap levels. In this Letter we use first-principles calculations to study the formation energies of NPDs. First we validate the numerical method by comparing the calculated defect formation energies with measured values reported in the literature. Then we calculate the formation energy of various NPDs in a number of InAs-GaSb SLS systems. From the calculated defect formation energies in SLS relative to that in constituent bulk material, the probability of defect presence in SLS can be inferred if we know the growth conditions of SLS with respect to those of the bulk material. Since the defects with much higher formation energy in SLS will be difficult to form, their energy levels in the SLS mini-gap will have little effect on device performance, even if the defect states lie in mid-gap. Together with our calculated defect energy level results, we can identify promising SLS designs for high-performing photodetectors.

Document Details

Document Type
Pub Defense Publication
Publication Date
Jun 01, 2017
Source ID
10.1063/1.4985136

Entities

People

  • Srini Krishnamurthy
  • Zhi-gang Yu

Organizations

  • Air Force Materiel Command
  • Washington State University

Tags

Fields of Study

  • Materials science

Readers

  • Computational Modeling and Simulation
  • Semiconductor Device Technology
  • Solar Photovoltaics and Thermoelectric Devices.

Technology Areas

  • AI & ML
  • AI & ML - Bayesian Inference