Optical properties of nanoporous gold foams

Abstract

We fabricated and experimentally studied Au nano-foams and Al2O3 scaffolds filled with Au nanoparticles (NPs). We found that while the reflectance spectra of Au nano-foams depended very little on the 8-10 nm Al2O3 ALD coating, the spectra were highly sensitive to annealing, which increased the sizes of voids and ligaments from 50-100 nm to ∼300 nm. The effective dielectric permittivities of the Au nano-foams and Al2O3 scaffolds with Au NPs were extremely high, ∼50. At the same time, Au nano-foams covered with a dielectric (MgF2) featured bright structural colors, calling for the model, which extends beyond the effective medium approximation.

Document Details

Document Type
Pub Defense Publication
Publication Date
Sep 01, 2018
Source ID
10.1063/1.5030128

Entities

People

  • J. K. Asane
  • M. M. Biener
  • V. Liberman
  • Zhen Qi

Organizations

  • Air Force Office of Scientific Research
  • Army Research Office
  • Lawrence Livermore National Laboratory
  • Massachusetts Institute of Technology
  • National Science Foundation
  • Norfolk State University
  • Office of the Secretary of Defense

Tags

Readers

  • Astronomy/Astrophysics
  • Nanocomposite Materials Science
  • Semiconductor Device Technology

Technology Areas

  • Biotechnology