Ultrafast photodissociation dynamics of 1,4-diiodobenzene
Abstract
The photodissociation dynamics of 1,4-diiodobenzene is investigated using ultrafast time-resolved photoelectron spectroscopy. Following excitation by laser pulses at 271 nm, the excited-state dynamics is probed by resonance-enhanced multiphoton ionization with 405 nm probe pulses. A progression of Rydberg states, which come into resonance sequentially, provide a fingerprint of the dissociation dynamics of the molecule. The initial excitation decays with a lifetime of 33 ± 4 fs, in good agreement with a previous study. The spectrum is interpreted by reference to ab initio calculations at the CASPT2(18,14) level, including spin-orbit coupling. We propose that both the 5B1 and 6B1 states are excited initially, and based on the calculations, we identify diabatic spin-orbit coupled states corresponding to the main dissociation pathways.
Document Details
- Document Type
- Pub Defense Publication
- Publication Date
- May 21, 2018
- Source ID
- 10.1063/1.5031787
Entities
People
- Adam Kirrander
- Asami Odate
- Brian Stankus
- David M Rogers
- Nikola Zotev
- Peter M. Weber
- Yan Gao
Organizations
- Army Research Office
- Brown University
- Carnegie Trust for the Universities of Scotland
- Leverhulme Trust
- Rhode Island Space Grant Consortium
- University of Edinburgh