Perspective: How to understand electronic friction
Abstract
Electronic friction is a correction to the Born-Oppenheimer approximation, whereby nuclei in motion experience a drag in the presence of a manifold of electronic states. The notion of electronic friction has a long history and has been (re-)discovered in the context of a wide variety of different chemical and physical systems including, but not limited to, surface scattering events, surface reactions or chemisorption, electrochemistry, and conduction through molecular-(or nano-) junctions. Over the years, quite a few different forms of electronic friction have been offered in the literature. In this perspective, we briefly review these developments of electronic friction, highlighting the fact that we can now isolate a single, unifying form for (Markovian) electronic friction. We also focus on the role of electron-electron interactions for understanding frictional effects and offer our thoughts on the strengths and weaknesses of using electronic friction to model dynamics in general.
Document Details
- Document Type
- Pub Defense Publication
- Publication Date
- Jun 15, 2018
- Source ID
- 10.1063/1.5035412
Entities
People
- Joseph E Subotnik
- Wenjie Dou
Organizations
- Air Force Office of Scientific Research
- University of Pennsylvania