High resistivity halide vapor phase homoepitaxial β-Ga2O3 films co-doped by silicon and nitrogen

Abstract

Semi-insulating halide vapor phase epitaxial β-Ga2O3 films without intentional dopants introduced during growth are demonstrated. The sheet resistance measured in the 340–480 K range yielded 268–134 kΩ/◻ and an activation energy of 0.81 eV. Room temperature capacitance-voltage measurements at 1 MHz showed evidence of an ultra-low free carrier concentration n-type film with a free carrier concentration near flatband (VFB ∼ 4.4 V) estimated to be <1014 cm−3, resulting in a high breakdown voltage of 2380 V (3.18 MV/cm) measured on a lateral diode without field termination. Secondary ion mass spectroscopy did not reveal Fe compensating species; however, an average Si concentration of about 5 × 1015 cm−3 and an N concentration of about 2 × 1017 cm−3 were detected, suggesting that N acceptors compensated Si donors to result in a nearly intrinsic β-Ga2O3 film. Photoionization spectroscopy suggested the presence of a deep acceptor-like level located at Ec −0.23 eV.

Document Details

Document Type
Pub Defense Publication
Publication Date
Nov 05, 2018
Source ID
10.1063/1.5045601

Entities

People

  • Akito Kuramata
  • Andrew D. Koehler
  • Daiki Wakimoto
  • Evan R. Glaser
  • Fritz J. Kub
  • Jaime A. Freitas Jr.
  • James C. Gallagher
  • Karl D. Hobart
  • Ken Goto
  • Kohei Sasaki
  • Marko J. Tadjer
  • Matty C. Specht
  • Quang T. Thieu
  • Shinya Watanabe
  • Travis J. Anderson

Organizations

  • American Society for Engineering Education
  • Office of Naval Research Global
  • Tamura Corporation
  • United States Naval Research Laboratory

Tags

Fields of Study

  • Materials science

Readers

  • Materials Science and Engineering.
  • Semiconductor Device Technology

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene