A room-temperature mid-infrared photodetector for on-chip molecular vibrational spectroscopy

Abstract

Infrared (IR) photodetection is of major scientific and technical interest since virtually all molecules exhibit characteristic vibrational modes in the mid-infrared region of the spectrum, giving rise to molecular spectroscopy and chemical imaging in this wavelength range. High-resolution IR spectroscopies, such as Fourier Transform IR spectroscopy, typically require large, bulky optical measurement systems and expensive photodetector components. Here, we present a high-responsivity photodetector for the mid-IR spectral region which operates at room temperature. Fabricated from silicon and aluminum, the photodetection mechanism is based on free carrier absorption, giving rise to a photoresponse rivalling commercially available cooled IR photodetectors. We demonstrate that infrared spectra of molecules deposited on this detector can be obtained by a direct electrical read-out. This work could pave the way for simple, fully integrated chemical sensors and other applications, such as chemical imaging, which would benefit from the combination of mid-IR detection, room-temperature operation, and ultracompact portability.

Document Details

Document Type
Pub Defense Publication
Publication Date
Sep 03, 2018
Source ID
10.1063/1.5045663

Entities

People

  • Benjamin Cerjan
  • Bob Zheng
  • Emilie Ringe
  • Hangqi Zhao
  • Naomi J. Halas
  • Peter Nordlander
  • Sadegh Yazdi

Organizations

  • Air Force Office of Scientific Research
  • Army Research Office
  • Defense Threat Reduction Agency
  • National Science Foundation
  • Rice University
  • Robert A. Welch Foundation

Tags

Fields of Study

  • Physics

Readers

  • Integrated Circuit Design and Technology.
  • Molecular Photonics/Laser Physics
  • Semiconductor Device Technology