The role of transient surface morphology on composition control in AlGaN layers and wells

Abstract

The mechanisms governing “compositional pulling” during the growth of AlxGa1−xN wells are investigated. Gallium-rich AlxGa1−xN wells grown on high dislocation density AlN/sapphire templates exhibit asymmetric and diffuse composition profiles, while those grown on low dislocation density native AlN substrates do not. Furthermore, strain in all AlxGa1−xN wells is found to be pseudomorphic, ruling it out as the dominating driving force. Rather, the high threading dislocation density of the AlN template is considered to play the defining role. We propose that a transient surface morphology is introduced during dislocation mediated spiral growth, which, in conjunction with process supersaturation, determines the Ga incorporation. These findings provide insights into compositional pulling in high Ga content AlxGa1−xN grown on AlN and provide a route to grow thicker wells with very abrupt interfaces on native AlN substrates.

Document Details

Document Type
Pub Defense Publication
Publication Date
Jan 21, 2019
Source ID
10.1063/1.5063933

Entities

People

  • J. Houston Dycus
  • James M. LeBeau
  • Ramón Collazo
  • Ronny Kirste
  • Seiji Mita
  • Shun Washiyama
  • Tim B. Eldred
  • Yan Guan
  • Zlatko Sitar

Organizations

  • Air Force Office of Scientific Research
  • Army Research Office
  • National Science Foundation
  • North Carolina State University
  • Office of Naval Research Global
  • United States Department of Energy

Tags

Fields of Study

  • Materials science

Readers

  • Materials Science and Engineering.
  • Semiconductor Device Technology

Technology Areas

  • Microelectronics