Electrical properties, structural properties, and deep trap spectra of thin α-Ga2O3 films grown by halide vapor phase epitaxy on basal plane sapphire substrates

Abstract

Undoped epitaxial films of α-Ga2O3 were grown on basal plane sapphire substrates by halide vapor phase epitaxy (HVPE) in three different modes: standard HVPE, HVPE with constant flow of Ga and pulsed supply of O2 (O2-control growth regime), and with constant flow of O2 and pulsed delivery of Ga (Ga-control growth fashion). The best crystalline quality as judged by x-ray symmetric and asymmetric reflection half-widths and by atomic force microscopy morphology profiling was obtained with the O2-control deposition, and these results appear to be the best so far reported for α-Ga2O3 films. All grown α-Ga2O3 epilayers were high-resistivity n-type, with the Fermi level pinned near Ec − 1 eV deep traps. Photoinduced current transient spectra also showed the existence in standard HVPE samples and samples grown under the O2-control pulsed growth conditions of deep hole traps with levels near Ev + 1.4 eV whose density was suppressed in the Ga-control pulsed HVPE samples. The levels of the dominant deep traps in these α-Ga2O3 samples are close to the position of dominant electron and hole traps in well documented β-Ga2O3 crystals and films.

Document Details

Document Type
Pub Defense Publication
Publication Date
Dec 01, 2018
Source ID
10.1063/1.5075718

Entities

People

  • A. Y. Polyakov
  • Dae‐Woo Jeon
  • Hoki Son
  • I. V. Shchemerov
  • In‐Hwan Lee
  • Jonghee Hwang
  • N. B. Smirnov
  • Stephen Pearton
  • А. I. Kochkova
  • А. В. Черных

Organizations

  • Defense Threat Reduction Agency
  • Korea University
  • Ministry of Education and Science of the Russian Federation
  • National Research Foundation of Korea
  • National University of Science and Technology
  • University of Florida

Tags

Fields of Study

  • Materials science

Readers

  • Materials Science and Engineering.
  • Semiconductor Device Technology

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene