Bandgap narrowing and Mott transition in Si-doped Al0.7Ga0.3N

Abstract

Deep ultraviolet light-emitting diodes (LEDs) composed of III-Nitride semiconductors need layers of heavy doping (>1 × 1019 cm−3) to overcome large dopant activation energies and maintain high electrical conductivity. This work reports that at doping densities of [Si] ∼1.5 × 1019/cm3 for n-Al0.7Ga0.3N, Burstein-Moss and bandgap renormalization effects result in a net reduction of the bandgap of ∼70 meV. At these doping levels, a transition to a metallic conductivity state is observed, with a vanishing of the effective dopant activation energy. The sheet and contact resistivities of Rsh,n = 0.045 Ω cm and ρc,n = 1.13 × 10−6 Ω cm2 are achieved, with uniform conductivity in the vertical direction. The results show that when heavily doped n-AlGaN cladding regions are used for high efficiency deep-UV LEDs or lasers, the accompanying bandgap narrowing reduces the window of optical transparency at the lowest wavelengths that can take advantage of high conductivity.

Document Details

Document Type
Pub Defense Publication
Publication Date
Mar 18, 2019
Source ID
10.1063/1.5086052

Entities

People

  • Alexander Chaney
  • Debdeep Jena
  • Huili Grace Xing
  • Kazuki Nomoto
  • S. M. Islam
  • Shyam Bharadwaj
  • Vladimir Protasenko

Organizations

  • Air Force Office of Scientific Research
  • Cornell University
  • National Science Foundation

Tags

Fields of Study

  • Materials science

Readers

  • Materials Science and Engineering.
  • Plasma Physics.
  • Quantum Dot Semiconductor Device Photonics and Graphene Optoelectronic Materials and THz Physics.

Technology Areas

  • Directed Energy
  • Directed Energy - Pulsed-Laser Deposition
  • Microelectronics
  • Microelectronics - Graphene